When astronomers study distant stars they actually look at ABSORPTION spectra rather than emission spectra. The sun radiates like a so-called "black body" with temperature around 5700K. The interactions between the particles create a different, much larger set of energy levels that permit a continuous rather than discrete spectrum. Also, you have enormous pressure, which forces all of the atoms to interact with one another in a way that they don't when they are in low-pressure gas form. In other words, you have a lot of H nuclei (ie protons) and a lot of electrons, and they aren't bound together to make a nice simple H atom. For one thing, the temperature is very high, so the atoms are ionized. The sun is not just a big ball of H atoms loosely floating around. To view the spectrum we need hydrogen in its gaseous form, so that the individual atoms are floating around, not interacting too much with one another. The discrete spectrum emitted by a H atom is a result of the energy levels within the atom, which arise from the way the electron interacts with the proton. Infrared photons are invisible to the human eye, but can be felt as "heat rays" emitted from a hot solid surface like a cooling stove element (a red-hot stove or oven element gives off a small amount of visible light, red, but most of the energy emitted is in the infrared range). However, all solids and liquids at room temperature emit and absorb long-wavelength radiation in the infrared (IR) range of the electromagnetic spectrum, and the spectra are continuous, described accurately by the formula for the Planck black body spectrum. metals like tungsten, or oxides like cerium oxide in lantern mantles) include visible radiation. Because solids and liquids have finite boiling points, the spectra of only a few (e.g. Because the electric force decreases as the square of the distance, it becomes weaker the farther apart the electric charged particles are, but there are many such particles, with the result that there are zillions of energy levels very close together, and transitions between all possible levels give rise to continuous spectra. The second case occurs in condensed states (solids and liquids), where the electrons are influenced by many, many electrons and nuclei in nearby atoms, and not just the closest ones. During these collisions, the electrons can gain or lose any amount of energy (within limits dictated by the temperature), so the spectrum is continuous (all frequencies or wavelengths of light are emitted or absorbed). The first occurs, for example, in plasmas like the Sun, where the temperatures are so high that the electrons are free to travel in straight lines until they encounter other electrons or positive ions. Continuous spectra (absorption or emission) are produced when (1) energy levels are not quantized, but continuous, or (2) when zillions of energy levels are so close they are essentially continuous. in outer space or in high-vacuum tubes) emit or absorb only certain frequencies of energy (photons). The measurements at 7μ give about 13.2× 10 − 40, which is five times that of HCl.Line spectra are produced when isolated atoms (e.g. Estimates of the moment of inertia of the molecule from various bands do not agree. If they are, it appears that the intensity of the zero branch increases with the order of the vibrational transition. The forms of the curves and the separations between maxima raise some doubts as to whether the higher frequency bands are second and third harmonics of the one at 14μ. There is a sharp single maximum at 3.564μ. Three others, less intense and unsymmetrical, are found at 4.756μ, 4.723μ and 4.79μ. Two maxima, very nearly symmetrical and of equal intensity, appear at 6.94μ and 7.23μ. Of these, the fundamental at 14μ can not be reached with the grating spectrometer at present, but the three others have been examined with specially ruled gratings giving higher dispersion than was previously employed. Infra-red absorption maxima due to hydrogen cyanide.-Four of the infrared bands due to HCN have been associated by Kratzer as fundamental and successive harmonics.
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